The most compelling moments in Scott Beck and Bryan Woods’ mostly sharp religious horror Heretic involve Mr. Reed, a cerebral theologian played with reptilian persuasiveness by Hugh Grant, intellectually sparring with two young Mormon evangelists. Grant, whose eager eyes and puckish smile wooed Renée Zellweger’s Bridget Jones and Julia Roberts’ Anna Scott (Notting Hill), uses his signature charm here to test the bounds of these junior missionaries’ beliefs. He imbues his character, a sinister recluse, with a well-intentioned disposition that soon reveals itself to be an unsettling trap. Heretic, which premiered at the Toronto International Film Festival before it hits theaters November 15, sells Grant as a convincing villain and makes you wonder why he hasn’t played more of them. 

Mr. Reed is the kind of guy whose intense gaze and off-color jokes betray a bizarre personality that’s initially easy to ignore. That’s what happens with Sisters Paxton (The Fablemans’ Chloe East) and Barnes (Yellowjackets’ Sophie Thatcher), two campaigners deployed by their chapter of The Church of Jesus Christ of Latter-day Saints to convert this curious soul. When the women reach his house —  at the top of a steep set of stairs integrated, Frank Lloyd Wright-style, into a grassy hill — they are eased by Mr. Reed’s candor and warmth. Most people treat the proselytizers like the plague. An early scene in which Sister Paxton is publicly humiliated by a group of teenagers captures their standing in this community. 

But Mr. Reed is different. He invites Sisters Paxton and Barnes to come inside, assures them that his wife is home (Mormon women can’t be alone with a man, they say) and even offers them blueberry pie. Never mind that his movements suggest some malevolence, that he can’t stop staring at a surgical mark on Sister Barnes’ arm or that his questions edge into more personal territory. So rare is his attentiveness to faith — he takes out his own annotated copy of the Mormon bible — that Sisters Paxton and Barnes decide to disregard their anxieties. That, of course, is a mistake. 

Beck and Woods, best known for creating A Quiet Place, confidently set up the initial chills of Heretic. Working with long-time Park Chan-wook cinematographer Chung-Hoon Chung and The Hunger Games production designer Philip Messina, the directorial duo focuses on the uncanny details of Mr. Reed’s home to establish a haunting tone. The wallpaper — a sickly yellow pattern — coupled with the lack of windows and the meticulous placement of the furniture cast doubt in both our and the girls’ minds about the trustworthiness of their host. 

The hostility of the space becomes more apparent the longer Sisters Paxton and Barnes chat with Mr. Reed. His enthusiasm verges on pushy, a sign that alerts Barnes, especially, to the danger of the situation. By the time the women realize they are in peril — the doors won’t open, the pie doesn’t exist — it is too late. Mr. Reed reveals himself to be a kind of religion obsessive, a self-taught scholar of faith and belief. His studies have led him to some disturbing conclusions, which he maps out for Paxton and Barnes in one of Heretic’s most fun and distinctive scenes. All that can be said is that it involves Monopoly, Jar Jar Binks, Radiohead and the Hollies.

Grant delivers his verbose musings with the composure of a professor and the velocity of a fanatic. He paces around the back room, where he has corralled his guests, and unveils props to support his points. Chung uses overhead shots to capture Mr. Reed’s desktop — a neatly organized tableau of religious texts and versions of the Monopoly board game  — which recalls a Renaissance triptych. 

Heretic is quite compelling in these early moments, which include Paxton and Barnes’ entrance as well as Mr. Reed’s presentation. East and Thatcher’s performances play a big role in keeping us hooked. If Grant is the wily villain, these actresses are the savvy horror protagonists worth rooting for. A gripping transition occurs as Mr. Reed intellectually ambushes these women, whose faith gets tested in the most extreme manner. East’s Sister Barnes pulls us in first with her shrewd observations and fearless reproach of Mr. Reed’s logic. But soon we’re watching Thatcher, who smartly leverages Paxton’s perceived naivety throughout the film.

Like The Assessment, another offering at this year’s Toronto International Film Festival, Heretic is most compelling as a three-character chamber drama. The charade between Mr. Reed, Paxton and Barnes helps to distracts from the screenplay, which wobbles under analytical pressure. Beck and Wood, at first, seem intent on interrogating the pitfalls of modern religion, but their narrative never goes all the way in its criticism. Once Mr. Reed moves on from his speeches and into more conventional horror-villain machinations, so too does Heretic distance itself from its most fiery theses. While it doesn’t totally diminish the thrill of watching Grant’s character revel in his own supposed cleverness, it does make the enterprise disappointingly shallow. A thread with a Mormon leader pursuing an earnest search for the missing girls similarly goes nowhere beyond a cheap joke done better earlier in the film. 

The relationship between Paxton, Barnes and Mr. Reed remains the most absorbing thread throughout Heretic. Even when the screenplay heads into deflating territory — trading potential acerbity for more neutral conclusions — their cat-and-mouse game keeps us curious and faithful.

It’s over for celebrity stylist and reality star Rachel Zoe and her husband, Rodger Berman. The couple is calling it quits.

“The Rachel Zoe Project” star announced Monday that she and Berman “have come to the mutual decision to end our marriage” after 33 years together and 26 years of marriage.

“We are incredibly proud of the loving family we have created and our countless memories together,” Zoe and Berman said in a joint statement posted on her Instagram. “Our number one priority has been and will always be our children. We are committed to co-parent our boys and to continue to work together within the many businesses we share. We ask for privacy during this time as we navigate this new chapter.”

The couple, who are both from New York, met in 1991 while both were attending George Washington University in Washington, D.C. Zoe was working as a hostess in a D.C. restaurant where he was working as a server. They got married in February 1998 and had two sons — 13-year-old Skyler and 10-year-old Kaius — who have been featured on the designer’s Bravo reality series and her Lifetime show “Fashionably Late With Rachel Zoe.”

The “Climbing in Heels” podcast host, who rose to fame in the early 2000s as a wardrobe stylist for the likes of Nicole Richie and Lindsay Lohan, became synonymous over the past couple of decades with the boho-meets-rocker chic aesthetic. She has expanded her brand as a fashion designer and TV personality over the past two decades and built up Rachel Zoe Inc. and the investment management company Rachel Zoe Ventures, among others. Berman, a former investment banker, is a co-founder and co-chief executive of the former company and managing partner of the latter.

It is unclear whether the couple has already filed for divorce.