Science
Half a pound of this powder can remove as much CO2 from the air as a tree, scientists say
A typical large tree can suck as much as 40 kilograms of carbon dioxide out of the air over the course of a year. Now scientists at UC Berkeley say they can do the same job with less than half a pound of a fluffy yellow powder.
The powder was designed to trap the greenhouse gas in its microscopic pores, then release it when it’s ready to be squirreled away someplace where it can’t contribute to global warming. In tests, the material was still in fine form after 100 such cycles, according to a study published Wednesday in the journal Nature.
“It performs beautifully,” said Omar Yaghi, a reticular chemist at UC Berkeley and the study’s senior author. “Based on the stability and the behavior of the material right now, we think it will go to thousands of cycles.”
Dubbed COF-999, the powder could be deployed in the kinds of large-scale direct air-capture plants that are starting to come online to reduce the amount of carbon in the atmosphere.
Keeping the concentration of atmospheric carbon dioxide below 450 parts per million is necessary to limit global warming to 2 degrees Celsius above preindustrial levels and prevent some of the most dire consequences of climate change, scientists say. Measurements taken at the Mauna Loa Observatory in Hawaii indicate that CO2 levels are currently around 423 ppm.
“You have to take CO2 from the air — there’s no way around it,” said Yaghi, who is also chief scientist at Berkeley’s Bakar Institute of Digital Materials for the Planet. “Even if we stop emitting CO2, we still need to take it out of the air. We don’t have any other options.”
Klaus Lackner, founding director of the Center for Negative Carbon Emissions at Arizona State University, agreed that direct air capture will become an important tool for sequestering carbon and cooling the planet once important hurdles have been overcome. The advances in the new study may help, he said.
“They are opening a door into a new family of approaches,” said Lackner, who wasn’t involved in the research.
When viewed under a scanning electron microscope, the powder resembles tiny basketballs with billions of holes, said study leader Zihui Zhou, a materials chemist who is working on his PhD at UC Berkeley.
The structures are held together by some of the strongest chemical bonds in nature, including the ones that turn carbon atoms into diamonds. Attached to the scaffolds are compounds called amines.
When air flows through the structures, most of its components pass by undisturbed. But the amines, which are basic, grab onto carbon dioxide, which is acidic.
Those CO2 molecules will stay put until scientists loosen them up by applying heat. Then they can vacuum them up for safekeeping, most likely by pumping them deep underground, Zhou said.
Once the carbon dioxide is removed from the powder, the entire process can begin again.
To test the carbon-clearing capabilities of COF-999, the researchers packed the powder into a stainless steel tube about the size of a straw and exposed it to outdoor Berkeley air for 20 days straight.
As it entered the tube, the Berkeley air contained CO2 in concentrations ranging from 410 ppm to 517 ppm. When it came out the other side, the scientists could not detect any carbon dioxide at all, Zhou said.
The powder has several advantages over other materials, according to its creators.
Its porous design increases its surface area, which means more places to hold onto CO2 molecules. As a result, it captures carbon dioxide at a rate that is “at least 10 times faster” than other materials used for direct air capture, Zhou said.
Team members have continued to make improvements, and they’re on track to double its capacity in the next year, Yaghi added.
Another plus is that COF-999 will loosen its hold on the CO2 when it’s heated to about 140 degrees F. Comparable materials must be heated to 250 degrees F to extract carbon, Zhou said.
The powder is more durable as well. Zhou said the team has tested a newer version that worked for 300 cycles before the experiment came to an end.
Lackner said that was a promising sign.
“Getting 100 cycles out and not seeing any deterioration suggests you can get thousands of cycles,” he said. “Whether you can get hundreds of thousands of cycles, we don’t know.”
To deploy it on an industrial scale will require designing some kind of large metal box that air can pass through without blowing all the powder away, Zhou said. Those boxes would need to be clustered together in quantities that evoke a modern-day chemical or petroleum plant.
Yaghi said a version of COF-999 could be ready for direct air capture plants within two years. He couldn’t estimate what it would cost to produce in bulk, but he said it doesn’t require any expensive or exotic materials.
Yaghi founded a company, Irvine-based Atoco, to commercialize his research on carbon capture and other technologies. Atoco helped fund the new study. (Other financial backers include the Bakar Institute and the King Abdulaziz City for Science and Technology.)
In addition, UC Berkeley has filed a patent application for COF-999, which names Yaghi and Zhou inventors.
Lackner said the entire direct air capture process will have to become “10 times cheaper than it is now” before it can make a real dent in the hundreds of billions of tons of carbon dioxide that scientists would love to scrub from the atmosphere.
A material that’s more efficient at collecting CO2 would help, but Lackner said he spends more time fretting about problems like the heat that’s lost when temperatures are raised to harvest the carbon so it can be injected underground.
“There are a thousand things that feed into this,” he said.
Science
Cluster of farmworkers diagnosed with rare animal-borne disease in Ventura County
A cluster of workers at Ventura County berry farms have been diagnosed with a rare disease often transmitted through sick animals’ urine, according to a public health advisory distributed to local doctors by county health officials Tuesday.
The bacterial infection, leptospirosis, has resulted in severe symptoms for some workers, including meningitis, an inflammation of the brain lining and spinal cord. Symptoms for mild cases included headaches and fevers.
The disease, which can be fatal, rarely spreads from human to human, according to the U.S. Centers for Disease Control and Prevention.
Ventura County Public Health has not given an official case count but said it had not identified any cases outside of the agriculture sector. The county’s agriculture commissioner was aware of 18 cases, the Ventura County Star reported.
The health department said it was first contacted by a local physician in October, who reported an unusual trend in symptoms among hospital patients.
After launching an investigation, the department identified leptospirosis as a probable cause of the illness and found most patients worked on caneberry farms that utilize hoop houses — greenhouse structures to shelter the crops.
As the investigation to identify any additional cases and the exact sources of exposure continues, Ventura County Public Health has asked healthcare providers to consider a leptospirosis diagnosis for sick agricultural workers, particularly berry harvesters.
Rodents are a common source and transmitter of disease, though other mammals — including livestock, cats and dogs — can transmit it as well.
The disease is spread through bodily fluids, such as urine, and is often contracted through cuts and abrasions that contact contaminated water and soil, where the bacteria can survive for months.
Humans can also contract the illness through contaminated food; however, the county health agency has found no known health risks to the general public, including through the contact or consumption of caneberries such as raspberries and blackberries.
Symptom onset typically occurs between two and 30 days after exposure, and symptoms can last for months if untreated, according to the CDC.
The illness often begins with mild symptoms, with fevers, chills, vomiting and headaches. Some cases can then enter a second, more severe phase that can result in kidney or liver failure.
Ventura County Public Health recommends agriculture and berry harvesters regularly rinse any cuts with soap and water and cover them with bandages. They also recommend wearing waterproof clothing and protection while working outdoors, including gloves and long-sleeve shirts and pants.
While there is no evidence of spread to the larger community, according to the department, residents should wash hands frequently and work to control rodents around their property if possible.
Pet owners can consult a veterinarian about leptospirosis vaccinations and should keep pets away from ponds, lakes and other natural bodies of water.
Science
Political stress: Can you stay engaged without sacrificing your mental health?
It’s been two weeks since Donald Trump won the presidential election, but Stacey Lamirand’s brain hasn’t stopped churning.
“I still think about the election all the time,” said the 60-year-old Bay Area resident, who wanted a Kamala Harris victory so badly that she flew to Pennsylvania and knocked on voters’ doors in the final days of the campaign. “I honestly don’t know what to do about that.”
Neither do the psychologists and political scientists who have been tracking the country’s slide toward toxic levels of partisanship.
Fully 69% of U.S. adults found the presidential election a significant source of stress in their lives, the American Psychological Assn. said in its latest Stress in America report.
The distress was present across the political spectrum, with 80% of Republicans, 79% of Democrats and 73% of independents surveyed saying they were stressed about the country’s future.
That’s unhealthy for the body politic — and for voters themselves. Stress can cause muscle tension, headaches, sleep problems and loss of appetite. Chronic stress can inflict more serious damage to the immune system and make people more vulnerable to heart attacks, strokes, diabetes, infertility, clinical anxiety, depression and other ailments.
In most circumstances, the sound medical advice is to disengage from the source of stress, therapists said. But when stress is coming from politics, that prescription pits the health of the individual against the health of the nation.
“I’m worried about people totally withdrawing from politics because it’s unpleasant,” said Aaron Weinschenk, a political scientist at the University of Wisconsin–Green Bay who studies political behavior and elections. “We don’t want them to do that. But we also don’t want them to feel sick.”
Modern life is full of stressors of all kinds: paying bills, pleasing difficult bosses, getting along with frenemies, caring for children or aging parents (or both).
The stress that stems from politics isn’t fundamentally different from other kinds of stress. What’s unique about it is the way it encompasses and enhances other sources of stress, said Brett Ford, a social psychologist at the University of Toronto who studies the link between emotions and political engagement.
For instance, she said, elections have the potential to make everyday stressors like money and health concerns more difficult to manage as candidates debate policies that could raise the price of gas or cut off access to certain kinds of medical care.
Layered on top of that is the fact that political disagreements have morphed into moral conflicts that are perceived as pitting good against evil.
“When someone comes into power who is not on the same page as you morally, that can hit very deeply,” Ford said.
Partisanship and polarization have raised the stakes as well. Voters who feel a strong connection to a political party become more invested in its success. That can make a loss at the ballot box feel like a personal defeat, she said.
There’s also the fact that we have limited control over the outcome of an election. A patient with heart disease can improve their prognosis by taking medicine, changing their diet, getting more exercise or quitting smoking. But a person with political stress is largely at the mercy of others.
“Politics is many forms of stress all rolled into one,” Ford said.
Weinschenk observed this firsthand the day after the election.
“I could feel it when I went into my classroom,” said the professor, whose research has found that people with political anxiety aren’t necessarily anxious in general. “I have a student who’s transgender and a couple of students who are gay. Their emotional state was so closed down.”
That’s almost to be expected in a place like Wisconsin, whose swing-state status caused residents to be bombarded with political messages. The more campaign ads a person is exposed to, the greater the risk of being diagnosed with anxiety, depression or another psychological ailment, according to a 2022 study in the journal PLOS One.
Political messages seem designed to keep voters “emotionally on edge,” said Vaile Wright, a licensed psychologist in Villa Park, Ill., and a member of the APA’s Stress in America team.
“It encourages emotion to drive our decision-making behavior, as opposed to logic,” Wright said. “When we’re really emotionally stimulated, it makes it so much more challenging to have civil conversation. For politicians, I think that’s powerful, because emotions can be very easily manipulated.”
Making voters feel anxious is a tried-and-true way to grab their attention, said Christopher Ojeda, a political scientist at UC Merced who studies mental health and politics.
“Feelings of anxiety can be mobilizing, definitely,” he said. “That’s why politicians make fear appeals — they want people to get engaged.”
On the other hand, “feelings of depression are demobilizing and take you out of the political system,” said Ojeda, author of “The Sad Citizen: How Politics is Depressing and Why it Matters.”
“What [these feelings] can tell you is, ‘Things aren’t going the way I want them to. Maybe I need to step back,’” he said.
Genessa Krasnow has been seeing a lot of that since the election.
The Seattle entrepreneur, who also campaigned for Harris, said it grates on her to see people laughing in restaurants “as if nothing had happened.” At a recent book club meeting, her fellow group members were willing to let her vent about politics for five minutes, but they weren’t interested in discussing ways they could counteract the incoming president.
“They’re in a state of disengagement,” said Krasnow, who is 56. She, meanwhile, is looking for new ways to reach young voters.
“I am exhausted. I am so sad,” she said. “But I don’t believe that disengaging is the answer.”
That’s the fundamental trade-off, Ojeda said, and there’s no one-size-fits-all solution.
“Everyone has to make a decision about how much engagement they can tolerate without undermining their psychological well-being,” he said.
Lamirand took steps to protect her mental health by cutting social media ties with people whose values aren’t aligned with hers. But she will remain politically active and expects to volunteer for phone-banking duty soon.
“Doing something is the only thing that allows me to feel better,” Lamirand said. “It allows me to feel some level of control.”
Ideally, Ford said, people would not have to choose between being politically active and preserving their mental health. She is investigating ways to help people feel hopeful, inspired and compassionate about political challenges, since these emotions can motivate action without triggering stress and anxiety.
“We want to counteract this pattern where the more involved you are, the worse you are,” Ford said.
The benefits would be felt across the political spectrum. In the APA survey, similar shares of Democrats, Republicans and independents agreed with statements like, “It causes me stress that politicians aren’t talking about the things that are most important to me,” and, “The political climate has caused strain between my family members and me.”
“Both sides are very invested in this country, and that is a good thing,” Wright said. “Antipathy and hopelessness really doesn’t serve us in the long run.”
Science
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